If it sounds weird to unexpectedly interview people, then that’s only because you’re thinking of them as interviews instead of conversations. The only thing people love talking about more than themselves is their problems. By taking an interest in the problems and minutia of their day, you’re already more interesting than 99% of the people they’ve ever met. Rule of thumb: If it’s not a formal meeting, you don’t need to make excuses about why you’re there or even mention that you’re starting a business. Just ask about their life.