The answer is that s (the standard deviation) is an estimate of the population standard deviation, and it is an unbiased estimate. Unbiased means that your sample estimate of the mean is just as likely to be a little higher than the population mean as it is to be a little lower. It is unbiased, though, only when we subtract 1 from n. By subtracting 1 from the denominator, we artificially force the standard deviation to be a tiny bit larger than it would be otherwise. Why would we want to do that? Because, as good scientists, we are conservative. Being conservative means that if we have to err
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