Genius: The Life and Science of Richard Feynman

by James Gleick

For Feynman, thinking in his spare time about the pure theory of particles and light, diffusion dovetailed peculiarly with quantum mechanics. The traditional diffusion equation bore a family resemblance to the standard Schrödinger equation; the crucial difference lay in a single exponent, where the quantum mechanical version was an imaginary factor, i. Lacking that i, diffusion was motion without inertia, motion without momentum. Individual molecules of perfume carry inertia, but their aggregate wafting through air, the sum of innumerable random collisions, does not. With the i, quantum mechanics could incorporate inertia, a particle’s memory of its past velocity. The imaginary factor in the exponent mingled velocity and time in the necessary way. In a sense, quantum mechanics was diffusion in imaginary time.