Einstein showed that although the number of atoms striking the Brownian particle from each direction is equal on the average, the fluctuations away from this average lead to unbalanced forces in random directions. In any random process, the relative fluctuations from an average value is inversely proportional to the square root of the number of samples—the smaller the sample, the bigger the fluctuations. For a large particle, the bulk pressure of the surrounding atoms is indeed evenly balanced, but for a small particle, the fluctuations in the number of impinging atoms is sufficient to propel
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