As zero temperature is approached the molecular disorder ceases to have any bearing on physical events. This fact was, by the way, not discovered by theory, but by carefully investigating chemical reactions over a wide range of temperatures and extrapolating the results to zero temperature – which cannot actually be reached. This is Walther Nernst’s famous ‘Heat Theorem’, which is sometimes, and not unduly, given the proud name of the ‘Third Law of Thermodynamics’ (the first being the energy principle, the second the entropy principle).
