Nevertheless, even though thermodynamics has been explained in terms of particles and forces, it continues to deal with emergent concepts like temperature and entropy that lose all meaning on the level of individual particles. Thermodynamics is more like a mode of reasoning than a body of universal physical law; wherever it applies it always allows us to justify the use of the same principles, but the explanation of why thermodynamics does apply to any particular system takes the form of a deduction using the methods of statistical mechanics from the details of what the system contains, and
...more