Because an error in experimental science is a mistake about the cause of something. Like an accurate observation, it is a matter of theory. Very little in nature is detectable by unaided human senses. Most of what happens is too fast or too slow, too big or too small, or too remote, or hidden behind opaque barriers, or operates on principles too different from anything that influenced our evolution. But in some cases we can arrange for such phenomena to become perceptible, via scientific instruments.